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Hydrazide Salts of Diโ€Picric Acid as Dense and Insensitive Energetic Materials

Abstract. Energetic dipicrate hydrazide salts were synthesized by combining picric acid (PA) as anion and carbohydrazide and oxalyldihydrazide as cations in stoichiometric amounts (2 : 1โ€…mol ratio). The structures of 2,2โ€ฒโ€carbonyldi(hydrazinโ€1โ€ium) bispicrate (1) and 2,2โ€ฒโ€(1,2โ€dioxoethaneโ€1,2โ€diyl)di(hydrazinโ€1โ€ium) bispicrate (2) were investigated by singleโ€crystal Xโ€ray diffraction analysis, illustrate that both crystals of 1 and 2 belong to the

Hydrazide Salts of Diโ€Picric Acid as Dense and Insensitive Energetic Materials

Abstract. Energetic dipicrate hydrazide salts were synthesized by combining picric acid (PA) as anion and carbohydrazide and oxalyldihydrazide as cations in stoichiometric amounts (2 : 1โ€…mol ratio). The structures of 2,2โ€ฒโ€carbonyldi(hydrazinโ€1โ€ium) bispicrate (1) and 2,2โ€ฒโ€(1,2โ€dioxoethaneโ€1,2โ€diyl)di(hydrazinโ€1โ€ium) bispicrate (2) were investigated by singleโ€crystal Xโ€ray diffraction analysis, illustrate that both crystals of 1 and 2 belong to the