Hydrazide Salts of DiโPicric Acid as Dense and Insensitive Energetic Materials
Abstract. Energetic dipicrate hydrazide salts were synthesized by combining picric acid (PA) as anion and carbohydrazide and oxalyldihydrazide as cations in stoichiometric amounts (2 : 1โ mol ratio). The structures of 2,2โฒโcarbonyldi(hydrazinโ1โium) bispicrate (1) and 2,2โฒโ(1,2โdioxoethaneโ1,2โdiyl)di(hydrazinโ1โium) bispicrate (2) were investigated by singleโcrystal Xโray diffraction analysis, illustrate that both crystals of 1 and 2 belong to the