Hydrazide Salts of Di‐Picric Acid as Dense and Insensitive Energetic Materials
Abstract. Energetic dipicrate hydrazide salts were synthesized by combining picric acid (PA) as anion and carbohydrazide and oxalyldihydrazide as cations in stoichiometric amounts (2 : 1 mol ratio). The structures of 2,2′‐carbonyldi(hydrazin‐1‐ium) bispicrate (1) and 2,2′‐(1,2‐dioxoethane‐1,2‐diyl)di(hydrazin‐1‐ium) bispicrate (2) were investigated by single‐crystal X‐ray diffraction analysis, illustrate that both crystals of 1 and 2 belong to the
